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William H. Breckenridge Department of Chemistry 315 S. 1400 East Rm
2020 (Note: Professor Breckenridge chose to take early retirement in 2005. He is still involved in science, however, for example in collaborations with scientists in both France and England. He hopes to continue his travels to France until he drops over dead.) |
Professor Breckenridge in Paris |
I. Addresses
Mailing: University of Utah
Department of Chemistry
315 S. 1400 East Rm 2020
Salt Lake City, Utah 84112
Email: breck@chem.utah.edu
Phone: (801) 581-8024
Fax: (801) 587-9919
II. Employment History
Bell
Laboratories, Murray Hill, New Jersey
Member
of Technical Staff, January 1970 - September 1971
Department
of Chemistry, University of Utah, Salt Lake City, Utah
Assistant
Professor, 1971-1976
Associate
Professor, 1976-1980
Professor,
1980-2005
Professor Emeritus, 2005
III. Educational
Background
Kansas
University, Lawrence, Kansas, 1959-1963,
B.S.,
Chemistry, with Honors and Highest Distinction
Leeds
University, Leeds, England, 1963-1964,
Graduate
Research, Physical Chemistry
Stanford
University, Stanford, California, 1964-1968,
Ph.D.,
Physical and Inorganic Chemistry
Cambridge
University, Cambridge, England, 1969,
Postdoctoral
Research, Physical Chemistry
IV. Early
Research Experience
University
of Kansas, 1962-1963:
Hot
Atom Chemistry
Advisor: Professor F. S. Rowland (Nobel Prize in
Chemistry, 1995)
Leeds
University, 1963-1964:
Photochemistry
in the Vacuum Ultraviolet
Advisors: Professor Sir F. S. Dainton, Dr. D. L.
Baulch
Stanford
University, 1964-1968:
Photochemistry,
Isotope Exchange, Gas Kinetics, Matrix Isolation of
Reactive
Species
Advisor: Professor Henry Taube (Nobel Prize in
Chemistry, 1983)
Thesis
Title: Reactions of Sulfur Atoms
Produced by
Photolysis
of Carbonyl Sulfide
Cambridge
University, 1969:
Flash
Photolysis, Kinetic Spectroscopy
Advisor: Dr. A. B. Callear
Bell
Laboratories, 1970:
Gas
Kinetics of Excited Species Using Flow Techniques with
EPR
Detection
Collaborator: Dr. T. A. Miller
V. Membership in Professional and Honorary Societies
American
Chemical Society
American
Physical Society
Phi
Beta Kappa
Phi
Lambda Upsilon
VI. Visiting
Positions
2007 Royal Society of England Travel Grant (North America Short Visit), for collaboration with Dr. Tim Wright, U. of Nottingham.
2005-onwards Scientific Collaboration with B. Soep (CEA, Saclay, France) and N. Shafizideh (U. of Paris-Sud, France)
2005-onwards Visiting Professor, U of Nottingham (collaboration with Dr. Tim Wright).
2001-2002 Visiting Senior Scholar, Atomic Energy Research Establishment, Saclay, France (sabbatical leave with J.-P. Mestdagh and B. Soep)
1993 Visiting Professor, Chemistry Research Promotion Center, National Taiwan University, Taipei, Taiwan
1985 Kipping Visiting Professor, University of Nottingham, Nottingham, England
1985 Professeur Associé, Université de Paris-Sud, Orsay, France (sabbatical leave with B. Soep)
1984 Visiting Research Professor, Max-Planck-Institut für Strömungsforschung, Göttingen, West Germany (sabbatical leave with Ch. Ottinger)
1977-1978 Visiting Scholar, Stanford University (sabbatical leave with R.N. Zare)
University of Utah
2005 W.H. Breckenridge Scholarship for Honors chemistry students was created by the Department of Chemistry in his honor. (Donations to this scholarship fund can be made by sending a check to The University of Utah, Department of Chemistry, W.H.B. Scholarship (c/o Shari Zinik), 315 South 1400 East, Rm. 2020, Salt Lake City, Utah 84112.
2005 Elected Professor Emeritus by colleagues in the Department of Chemistry.
2005 Calvin S. and JeNeal N. Hatch Prize
in Teaching (only one award given per year to all faculty at the University of
Utah)
2003 University of Utah
Distinguished Scholarly and Creative Research Award (given to only three
faculty per year, across all departments)
2001 University of
Utah Faculty Fellow Award (semester=s
leave with pay for a research project at Saclay, France).
1999 Elected
Fellow of the American Physical Society
1994 University
of Utah Presidential Teaching Scholar Award
1992 University of Utah
Distinguished Teaching Award (given to only three faculty per year, across all
departments)
1990 Robert W. Parry Teaching Award
in Chemistry
(First recipient of an endowed award in the Department
of Chemistry.)
1985 J. S.
Guggenheim Fellow
1984 Senior
Fulbright Fellow (Germany)
1984 Student
Advisory Committee Teaching Award
(Outstanding teacher in the
Department of Chemistry for 1983-1984 academic year)
1980 David P.
Gardner Faculty Fellow
1978 National Science Foundation Science Faculty Development Grant
(Sabbatical leave at Stanford
University)
1974 Student
Advisory Committee Teaching Award
(Outstanding teacher in the
Department of Chemistry for 1973-1974 academic year)
1973 Camille
and Henry Dreyfus Teacher-Scholar, 1973-1978
Cambridge University
1969 North Atlantic Treaty Organization (NATO) Postdoctoral Fellow (Recipients were selected by the National Science Foundation.)
Stanford University
1965-1968 National
Science Foundation Fellow
Leeds University
1963-1964 Fulbright
Fellow, England (Honorary Woodrow Wilson Fellow)
Kansas
University
1963 American Institute of Chemists Award (to the most outstanding graduating senior majoring in chemistry)
1963 Hamilton Award (science major who contributed most to the study of the humanities)
1961-1963 Summerfield Scholar
1955-1959 Quarterback of the undefeated LRHS football team, 1958.
Elected president of the senior class, 1958.
Valedictorian, class of 1959.
VIII. Scientific Publications
1. W.H.
Breckenridge, John W. Root and F.S. Rowland, "Recoil Tritium
Reactions: Variation in Hot Abstraction
Yield with C-H Bond Type," J. Chem. Phys. 39, 2374 (1963).
2. J.W.
Root, W.H. Breckenridge and F.S. Rowland, "Abstraction of Hydrogen Atoms
by Energetic Recoil Tritium Atoms:
Correlation with C-H Bond-Dissociation Energies in Hydrocarbons," J.
Chem. Phys. 43, 3694 (1965).
3. D.L.
Baulch and W.H. Breckenridge, "Isotope Exchange of O(1D) with
CO2," Trans. Faraday Soc. 62, 2768 (1966).
4. E.
Weissberger, W.H. Breckenridge and Henry Taube, "The Reaction of O(1D)
with CO2 at Low Temperatures," J. Chem. Phys. 47,
1764 (1967).
5. W.H.
Breckenridge and Henry Taube, "The Ultraviolet Absorption Spectrum of
Carbonyl Sulfide," J. Chem. Phys. 52, 1713 (1970).
6. W.H.
Breckenridge and Henry Taube, "Some Reactions of Ground-State (3P)
and Electronically Excited (1D) Sulfur Atoms," J. Chem.
Phys. 53, 1750 (1970).
7. W.H.
Breckenridge and A.B. Callear, "Flash Spectroscopy with Cadmium Resonance
Radiation," Chem. Phys. Lett. 5, 17 (1970).
8. W.H.
Breckenridge and A.B. Callear, "Flash Spectroscopy with 2288 Å and 3261 Å
Cadmium Resonance Radiation," Trans. Faraday Soc. 67, 2009
(1971).
9. W.H.
Breckenridge and R.J. Donovan, "Reaction of S(31D2)
with N2O," Chem. Phys. Lett. 11, 520 (1971).
10. W.H.
Breckenridge and T.A. Miller, "A Kinetic Study by EPR of the Production
and Decay of SO(1Δ) in the Reaction of O2(1Δg)
with SO(3Σ-)" J. Chem. Phys. 56,
465 (1972).
11. W.H.
Breckenridge and T.A. Miller, "The Determination by Gas Phase EPR of the
Absolute Concentration of Species Undergoing Electric Dipole Transitions,"
J. Chem. Phys. 56, 475 (1972).
12. W.H.
Breckenridge and T.A. Miller, "Detection of Metastable 3P Argon
Atoms by Gas Phase EPR," Chem. Phys. Lett. 12, 437 (1972).
13. T.J.
Cook, B.R. Zegarski, W.H. Breckenridge and T.A. Miller, "Gas Phase EPR of
Vibrationally Excited O2," J. Chem. Phys. 58,
1548 (1973).
14. W.H.
Breckenridge and T.W. Broadbent, "Cross-Sections for Quenching of Cd(3PJ)
as Determined by Resonance Radiation Flash Photolysis," Chem. Phys.
Lett. 29, 421 (1974).
15. W.H.
Breckenridge, W.S. Kolln and D.S. Moore, "Reactions of Carbon
Monosulfide. I. An Experimental Kinetic Technique and a
Study of the Reaction of CS with O2," Chem. Phys. Lett. 32,
290 (1975).
16. W.H.
Breckenridge, T. W. Broadbent and D.S. Moore, "A Determination by
Resonance-Radiation Flash Photolysis of the Absolute Reaction Rates of Excited
Cadmium Cd(5P0,1) Atoms with Several Gases," J.
Phys. Chem. 79, 1233 (1975).
17. R.P.
Blickensderfer, W.H. Breckenridge and D.S. Moore, "A Direct Determination
of Absolute Quenching Cross-Sections for Mg(3PJ) Using
Pulsed Tunable Dye Laser Excitation," J. Chem. Phys. 63,
3681 (1975).
18. R.P. Blickensderfer,
W.H. Breckenridge and J.P. Simons, "The Diffusion Theory of Imprisonment
of Atomic Resonance Radiation at Low Opacities," J. Phys. Chem. 80,
653 (1976).
19. G.T.
Bida, W.H. Breckenridge and W.S. Kolln, "A Kinetic Study of the Very Fast
Reaction: O(3P) + CS 6 CO + S(3P)," J. Chem. Phys. 64, 3296
(1976).
20. W.H.
Breckenridge and J. FitzPatrick, "Production of NO(A2Σ+,
v=0) by Electronic Energy Transfer Between Cd(1P1) and
NO(X2Π)," J. Phys. Chem. 80, 1955 (1976).
21. W.H.
Breckenridge, R.P. Blickensderfer and J. FitzPatrick, "Near-Resonant
Electronic Energy Transfer Between Zn(1P1) and NO(X2Π),"
J. Phys. Chem. 80, 1963 (1976).
22. W.H.
Breckenridge and A.M. Renlund, "Quenching of Excited Cadmium (1P1)
Atoms by Several Molecules. Cross-Sections
and Chemical and Physical Exit-Channels," J. Phys. Chem. 82,
1474 (1978).
23. W.H.
Breckenridge and A.M. Renlund, "Reaction of Excited Cadmium (3PJ)
and Cadmium (1P1) Atoms with H2, HD, and D2. Quenching Cross-Sections and CdH (CdD)
Yields," J. Phys. Chem. 82, 1484 (1978).
24. W.H.
Breckenridge, O. Kim Malmin, W.L. Nikolai and D. Oba, "A Rapid
'Pump-and-Probe' Laser Technique for Determining State-Resolved Product
Distributions," Chem. Phys. Lett. 59, 38 (1978).
25. W.H.
Breckenridge and A.M. Renlund, "The Reaction of Excited Cadmium (3PJ)
Atoms with Alkane Hydrocarbons.
Quenching Cross-Sections and Primary CdH Yields," J. Phys. Chem.
83, 303 (1979).
26. W.H.
Breckenridge, R.P. Blickensderfer, John FitzPatrick and D. Oba, "Near
Resonant Electronic Energy Transfer:
Initial Rotational State Populations of NO(A2Σ+,
v'=0,1) Produced by Energy Transfer from Zn(1P1)," J.
Chem. Phys. 70, 4751 (1979).
27. W.H.
Breckenridge, R.J. Donovan and O. Kim Malmin, "Laser Excitation of Cd(1P1). Absolute Quenching Cross-Sections and
Branching Ratios for the Process: Cd(1P1)
+ M 6 Cd(3PJ) + M," Chem.
Phys. Lett. 62, 608 (1979).
28. W.H.
Breckenridge and A.M. Renlund, "Collisional Quenching of Electronically
Excited Zinc Atoms. Cross Sections and Exit Channels," J. Phys. Chem.
83, 1145 (1979).
29. W.H.
Breckenridge, G.T. Bida and W.S. Kolln, "Catalysis by Iron Pentacarbonyl
of the Polymerization of Carbon Monosulfide in a Flow Tube at Low
Pressures," J. Phys. Chem. 83, 1150 (1979).
30. R.J. Donovan,
H.M. Gillespie, W.H. Breckenridge, and C. Fotakis, "Isotope Effects in the
Quenching of Electronically Excited Atoms:
Quenching of I(52P) by Methane and Deuteromethanes Studied by
Time-resolved Resonance Fluorescence," J.C.S. Far. Trans. II, 75,
1557 (1979).
31. W.H.
Breckenridge and O. Kim Malmin, "The Initial Distributions of Cd(3P0,1,2)
Electronic States in the Collisional Deactivation of Cd(1P1)
by Alkane Hydrocarbons," Chem. Phys. Lett. 68, 341 (1979).
32. W.H.
Breckenridge and D. Oba, "Initial Rotational State Product Distributions
Using the Pump-and-Probe Laser Technique," Chem. Phys. Lett. 72,
455 (1980).
33. W.H.
Breckenridge and W.L. Nikolai, "Temperature Dependence of the Quenching of
Mg(3PJ) by H2: Evidence for a Change from Physical to Chemical Exit- Channel
Control," J. Chem. Phys. 73, 2763 (1980).
34. W.H.
Breckenridge, Noah Adams, and Jack Simons, "A Theoretical Study of the
Reaction of Mg(3s3p3P) with H2," Chem. Phys. 56,
327 (1981).
35. W.H.
Breckenridge, W.L. Nikolai and J. Stewart, "Triplet-Triplet Energy-Pooling
Processes in Magnesium Vapor," J. Chem. Phys. 74, 2073
(1981).
36. W.H.
Breckenridge and O. Kim Malmin, "State-to-State Studies of the Collisional
Quenching of Electronically Excited Cd(1P1) Atoms," J.
Chem. Phys. 74, 3307, (1981).
37. W.H.
Breckenridge and H. Umemoto, "Laser Studies of the Collisional Quenching
of Electronically Excited Mg(3s3p1P1) Atoms," J.
Chem. Phys. 75, 698 (1981).
38. W.H.
Breckenridge and H. Umemoto, "Bimodal Rotational Quantum State Distribution
of MgH(X2Σ+,v=0) in the Reaction of Mg(3s3p1P1)
with H2: Evidence for
Microscopic Branching," J. Chem. Phys. 75, 4153 (1981).
39. W.H.
Breckenridge and N. Sinai, "Pulsed Laser Photolysis of Chromium
Hexacarbonyl in the Gas Phase," J. Phys. Chem. 85, 3557
(1981).
40. W.H.
Breckenridge and O.K. Malmin, "The Collisional Intramultiplet Relaxation
of Cd(5s5p3P0,1,2) by Alkane Hydrocarbons," J.
Chem. Phys. 76, 1812 (1982).
41. R.
Blickensderfer, K. Jordan, N. Adams, and W.H. Breckenridge, "Complexes of
Be(2s2p3P,1P) and Mg(3s3p3P,1P)
with H2: Implications for
the Mg(1P) + H2 6 MgH(2Σ)
+ H(2S) Reaction," J. Phys. Chem. 86, 1930
(1982).
42. W.H.
Breckenridge and J. Stewart, "The Temperature Dependence of the Quenching
of Mg(3PJ) by H2 and D2: Endoergic Chemical Reaction as
Rate-limiting," J. Chem. Phys. 77, 4469 (1982).
43. W.H.
Breckenridge and H. Umemoto, "Reaction of Mg(3s3p1P1)
with a Variety of Alkyl C-H Bonds:
Identical Initial MgH(X2Σ+,v=0) Rotational
Quantum State Distributions," J. Chem. Phys. 77, 4464
(1982).
44. W.H.
Breckenridge and H. Umemoto, "Absolute Cross-Sections for the Quenching of
Excited Ca(4s4p1P1) by Several Molecules," Chem.
Phys. Lett. 93, 387 (1982).
45. W.H.
Breckenridge and H. Umemoto, "Collisional Quenching of Electronically
Excited Metal Atoms," The Dynamics of the Excited State, ed. K.
Lawley, (Advances in Chemical Physics, Vol. 50, Wiley, 1982).
46. W.H.
Breckenridge and H. Umemoto, "Initial Distributions of Vibrational and
Rotational Quantum States of MgO(X1Σ+) in the
Reaction of Mg(3s3p 1P1) with CO2," J.
Phys. Chem. 87, 476 (1983).
47. W.H.
Breckenridge and H. Umemoto, "Reactions of Mg(1S0),
Mg(3PJ), and Mg(1P1) with Diatomic
and Triatomic Oxidants," J. Phys. Chem. 87, 1804 (1983).
48. W.H.
Breckenridge and H. Umemoto, "The Effective Delay Time in Pump-and-Probe
Measurements," J. Chem. Phys. 79, 745 (1983).
49. W.H.
Breckenridge and H. Umemoto, "Measurement of Unrelaxed Rotational
Distributions Using the Laser Pump-and-Probe Technique," Chem. Phys.
Lett. 101, 377 (1983).
50. W.H.
Breckenridge, "Reactions of Electronically Excited Atoms," Reactions
of Small Transient Species, M. Clyne and A. Fontijn, eds., Academic
Press, 1983.
51. W.H.
Breckenridge and H. Umemoto, "Nascent Internal Energy Distributions of
MgH(MgD) in the Reaction of Mg(3s3p1P1) with H2(D2),"
J. Chem. Phys. 80, 4168 (1984).
52. W.H.
Breckenridge and H. Umemoto, "Nascent Internal Energy Distributions of MgH
Produced in the Reactions of Mg(3s3p1P1) with a Variety of
Polyatomic Molecules," J. Chem. Phys. 81, 3852 (1984).
53. A.
Kowalski, M. Czajkowski, and W.H. Breckenridge, "Laser Excitation Spectrum
of the Og+(X1Σg+) - Ou+(3Πu)
Transition in Cd2," Chem. Phys. Lett. 119, 368
(1985).
54. A. Kowalski,
M. Czajkowski, and W.H. Breckenridge, "Excitation Spectra of CdNe, CdAr,
and CdKr Molecules in a Supersonic Jet," Chem. Phys. Lett. 121,
217 (1985).
55. John
G. McCaffrey, J. Mark Parnis, Geoffrey A. Ozin, and W.H. Breckenridge,
"Photochemical Synthesis of Magnesium Dihydride (MgH2) and
Methyl Magnesium Hydride (CH3MgH) in Cryogenic Matrices," J.
Phys. Chem. 89, 4945 (1985).
56. W.H.
Breckenridge, M.-C. Duval, C. Jouvet, and B. Soep, "Laser Double-Resonance
Studies of Rydberg States of HgAr," Chem. Phys. Lett. 122,
181 (1985).
57. W.H.
Breckenridge and J. Wang, "Initial Internal Energy Distributions of ZnH
(ZnD) Produced in the Reaction of Zn(3P1) with H2,
HD, and D2," Chem. Phys. Lett. 123, 17 (1986).
58. W.H. Breckenridge,
H. Umemoto, and J. Wang, "Initial Internal Energy Distributions of CdH
(CdD) Produced in the Reaction of Cd(3P1) with H2,
HD, and D2," Chem. Phys. Lett. 123, 23 (1986).
59. W.H.
Breckenridge, C. Jouvet, and B. Soep, "Orbitally Selective Chemical
Reaction in Hg-H2 Van der Waals Complexes," J. Chem. Phys.
84, 1443 (1986).
60. W. H.
Breckenridge and G. M. Stewart, "Pulsed Laser Photolysis of Chromium
Hexacarbonyl in the Gas Phase," J. Am. Chem. Soc. 108, 364
(1986).
61. W.H.
Breckenridge, D. Oba, and W. Nikolai, "Chemical and Physical Exit Channels
in the Quenching of Cd(5s5p 1P1) by Several
Molecules." J. Phys. Chem. 90, 5724 (1986).
62. M.-C.
Duval, O. Benoist D'Azy, W.H. Breckenridge, C. Jouvet, and B. Soep, "The
Structure of Several Electronic States of the Hg-Ar Complex as Determined by
Laser Double Resonance in a Supersonic Jet," J. Chem. Phys. 85,
6324 (1986).
63. A.
Kowalski, D. Funk, and W. H. Breckenridge, "Excitation Spectra of CaAr,
SrAr, and BaAr in a Supersonic Jet," Chem. Phys. Lett. 132,
263 (1986).
64. W.H.
Breckenridge and J.-H. Wang, "Dynamics of the Reactions of Mg(3s3p1P1)
with H2, HD, and D2: Rotational Quantum State
Distributions of MgH(MgD) Products," Chem. Phys. Lett. 137,
195 (1987).
65. W.H.
Breckenridge and J.-H. Wang, "Dynamics of the Reactions of Zn(4s4p3P1)
with H2, HD, and D2: Rotational and Vibrational Quantum
State Distributions of ZnH (ZnD) Products," J. Chem. Phys. 87,
2630 (1987).
66. G.
Chalasinski, D.J. Funk, J. Simons, and W.H. Breckenridge, "Møller-Plesset
Perturbation Theory for Van Der Waals Complexes Bound by Electron Correlation
Effects: Ground States of the Ar and Mg Dimers," J. Chem. Phys. 87,
3569 (1987).
67. W.H.
Breckenridge and J.-H. Wang, "The Lack of Leaving-Atom Isotope Effects on
Rotational State Distributions in M* + H2(HD) 6 MH(v,N) + H(D) Reactions: 'Half-Collision' Classical Trajectories on
Model H-M-H Anisotropic Potential Surfaces," Chem. Phys. Lett. 139,
28 (1987).
68. W.H.
Breckenridge, O. Benoist d'Azy, M.C. Duval, C. Jouvet, and B. Soep,
"Excited Van Der Waals Complexes as a Probe for Intermediate States in
Collisions," NATO ASI Ser., Ser. C, 200, 149-62 (1987).
69. W.H.
Breckenridge, M.C. Duval, C. Jouvet, and B. Soep, "Reactions in Van der
Waals Complexes. An Experimental
Approach to the Reactive Surfaces of Hg(3P1) + H2,"
J. de Chim. Physique 84, 381 (1987).
70. W.H.
Breckenridge, M.C. Duval, C. Jouvet and B. Soep, "Structure and Dynamics
of Mercury Van der Waals Complexes," NATO ASI Ser., Ser. C, 212,
213-29 (1987).
71. W.H.
Breckenridge and C.N. Merrow, "Nascent Distributions of Ca(4s3d1D2),
Ca(4s3d3DJ), and Ca(4s4p3PJ)
Quantum States in the Collisional Deactivation of Ca(4s4p1P1)
by the Rare Gases," J. Chem. Phys. 88, 2320 (1988).
72. W.H.
Breckenridge and C.N. Merrow, "Exclusive Production of Ba(6s6p3P2)
in the Collisional Deactivation of Ba(6s6p1P1) by the
Rare Gases," J. Chem. Phys. 88, 2329 (1988).
73. A.
Kvaran, D.J. Funk, A. Kowalski, and W.H. Breckenridge, "Spectroscopic
Characterization of the X(10+) and A(30+)
States of CdNe, CdAr, CdKr, and CdXe," J. Chem. Phys. 89,
6069 (1988).
74. I.
Wallace, R.R. Bennett, and W.H. Breckenridge, "Spectroscopic
Characterization of the X1Σ0+ and
C1Π1 States of the ZnAr van der Waals
Molecule," Chem. Phys. Lett. 153, 127 (1988).
75. Th.
Glenewinkel-Meyer, A. Kowalski, B. Müller, Ch. Ottinger, and W.H. Breckenridge,
"Emission Spectra and Electronic Structure of Group IIIa Monohalide
Cations," J. Chem. Phys. 89, 7112 (1988).
76. R.R.
Bennett, J.G. McCaffrey, I. Wallace, D.J. Funk, A. Kowalski, and W.H.
Breckenridge, "A Laser Spectroscopic Study of the X1Σ0+-C1Π1
Transition of MgAr: Evidence for Λ-type Doubling," J. Chem.
Phys. 90, 2139 (1989).
77. D.J.
Funk, A. Kvaran, and W.H. Breckenridge, "Spectroscopic Characterization of
the Lowest Singlet States of CdNe, CdAr, and CdKr," J. Chem. Phys. 90,
2915 (1989).
78. D.J.
Funk and W.H. Breckenridge, "Half-Collision Dynamics: Exclusive Production
of Cd(5s5p3P2) From the Predissociation of Cd(5s5p1P1)@Xe Electronic States," J. Chem. Phys. 90, 2927
(1989).
79. J.G.
McCaffrey, R.R. Bennett, M.D. Morse, and W.H. Breckenridge, "Laser
Excitation Spectroscopy of the A and B States of Jet-Cooled Copper Dimer:
Evidence for Large Electronic Isotope Shifts," J. Chem. Phys. 91,
92 (1989).
80. D.J.
Funk, W.H. Breckenridge, Jack Simons, and G. Chalasinski, "MPPT
Calculation of Alkaline Earth-Rare Gas Complexes: Ground States of Mg@He and Mg@Ar," J. Chem. Phys. 91, 1114
(1989).
81. C.
Jouvet, M.C. Duval, B. Soep, W.H. Breckenridge, and C. Whitham, "Orbital
Orientation in van der Waals Reactions," J. Chem. Soc., Faraday Trans.
2, 85, 1133 (1989).
82. W.H.
Breckenridge, "Chemical Reactions and Energy Transfer Processes of Electronically
Excited Group IIb Metal Atoms: Full Collisions and Half Collisions," Accounts
of Chemical Research, 22, 21 (1989).
83. C.
Jouvet, M.C. Duval, W.H. Breckenridge and B. Soep, "Reaction in van der
Waals Complexes," pp. 579-593 in Spectral Lineshapes, J. Szudy,
ed., Elsevier, Amsterdam and Ossolineum, Wroclaw, Poland (1989).
84. R.R.
Bennett and W.H. Breckenridge, "Spectroscopic Characterization of the ã3Π0-,
3Π2, and E3Σ+
States of ZnAr," J. Chem. Phys. 92, 1588 (1990).
85. R.R. Bennett,
J.G. McCaffrey, and W.H. Breckenridge, "A Spectroscopic Characterization
of the ã3Π0-, A3Π0+, and
E3Σ+ States of the MgAr van der Waals
Molecule," J. Chem. Phys. 92, 2740 (1990).
86. I.
Wallace, J. Kaup, and W.H. Breckenridge, "Excitation of Zn(4s4p1P1)
Within the Zn@Xe van der Waals Complex: Effect of p-orbital Alignment on the Production of Zn(4s4p3PJ),"
J. Phys. Chem. 95, 8060 (1991)
87. M.-C.
Duval, B. Soep, and W.H. Breckenridge, "Bonding in Complexes of Hg(6s6s1S0)
and Hg(6s6p3P1) with Rare-Gas Atoms and Small
Molecules: From Physical to Chemical
Interactions," J. Phys. Chem. 95, 7145 (1991) (Invited
Feature Article).
88. I.
Wallace, J. Ryter, and W.H. Breckenridge, "Spectroscopic characterization
of the X1Σ
and
C1Π1 states of the ZnKr molecule," J. Chem.
Phys. 96, 136 (1992).
89. R.R.
Bennett and W.H. Breckenridge, "Van der Waals bonding in the lowest
electronic states of MgAr, ZnAr, CdAr, and HgAr: Spectroscopic characterization
of the b3Π2 and e3Σ+
states of the CdAr molecule," J. Chem. Phys. 96, 882 (1992).
90. Z. Fu,
S. Massick, J.G. Kaup, O. Benoist d'Azy, and W.H. Breckenridge,
"Spectroscopic Characterization of the X2Π1/2,
B2Σ1/2, and H2Σ1/2 States
of AlKr," J. Chem. Phys. 97, 1683 (1992).
91. I.
Wallace and W.H. Breckenridge, "Half-Collision Studies: Action Spectroscopy of Energy Transfer
Within the Cd@CH4 Van der Waals Complex," J.
Chem. Phys. 97, 2318 (1992).
92. I.
Wallace, D.J. Funk, J.G. Kaup, and W.H. Breckenridge, "Half-Collision
Studies of Singlet-to-Triplet Energy Transfer:
Action Spectroscopy and Predissociation Dynamics of Electronically
Excited Cd@H2 and Cd@D2
Complexes," J. Chem. Phys. 97, 3135 (1992).
93. I.
Wallace, D.J. Funk, J.G. Kaup, and W.H. Breckenridge, "The Interactions of
Metal Atoms with Xe, CH4, and H2: Half Collision Studies," in Gas
Phase Metal Reactions, ed. A. Fontijn (Elsevier, 1992).
94. S.
Bililign, M.D. Morse, and W.H. Breckenridge, "Predissociation Lifetimes of
Vibrational Levels of the Excited 1B1 (K = 0) Electronic States of Cd@H2
and Cd@D2 Complexes," J. Chem. Phys. 98,
2115 (1993).
95. I.
Wallace and W.H. Breckenridge, "Spectroscopic Characterization of the X1Σ+
and C1Π States of the Mg@Ne
Molecule," J. Chem. Phys. 98, 2768 (1993).
96. S. Bililign,
M. Gutowski, Jack Simons, and W.H. Breckenridge, "Singlet-to-Triplet
Energy Transfer via 1Π1/3Σ Curve Crossings in Group 2 and 12 Metal-Atom/Rare-Gas Systems," J.
Chem. Phys. 99, 3815 (1993).
97. W.H. Breckenridge,
I. Wallace, D. J. Funk, J.G. Kaup, M. Morse, and S. Bililign,
"Half-Collision Studies of Singlet-to-Triplet Energy Transfer: Action
Spectroscopy and Predissociation Dynamics of Electronically Excited Cd@H2 and Cd@D2
Complexes," Proc. SPIEE - Int. Soc. Opt. Eng. 1858, 247
(1993).
98. J.G.
McCaffrey, D.J. Funk, and W.H. Breckenridge, "Characterization of the
First Excited 1Π1 State and the Ground X1Σ+
State of Mg@Xe. I. Analysis of the 1Π1 7 X1Σ+ Bound-bound Transition," J.
Chem. Phys. 99, 9472 (1993).
99. J.G.
McCaffrey, D.J. Funk, and W.H. Breckenridge, "Characterization of the
First Excited 1Π1 State and the Ground X1Σ+
State of Mg@Xe. II. Analysis of 1Π1 6 1Σ+ Bound-free Emission Spectra," J.
Chem. Phys. 100, 955 (1994).
100. S.
Bililign, M. Gutowski, Jack Simons, and W.H. Breckenridge, "Potential
Energy Curves of M(np 2P)@RG(2Π)
Excited States and M+@RG Ground States
(M = Li, Na; RG = He, Ne)," J. Chem. Phys. 100, 8212 (1994).
101. W.H. Breckenridge,
"Singlet-to-Triplet Energy Transfer Within M@RG Van
der Waals Complexes (M = Metal, RG = Rare-Gas)," in International
Reviews in Physical Chemistry, 13, 291 (1994).
102. J.G.
Kaup, S. Bililign, and W.H. Breckenridge, "Full- and Half-Collision
Studies of Metal Atom Singlet-to-Triplet Deactivation Induced by Rare Gas
Atoms," J. Phys. Chem. 99, 7878 (1995).
103. J.G.
Kaup and W.H. Breckenridge, "Singlet-to-Triplet Energy Transfer Within
M(RG)n van der Waals Clusters (M = Mg, Zn; RG = Ar, Kr, Xe)," J.
Phys. Chem. 99, 13701 (1995).
104. I. Wallace,
S. Bililign, D.J. Funk, J.G. Kaup, M.D. Morse, and W.H. Breckenridge,
"Half-Collision Studies of Singlet-to-Triplet Energy Transfer Within
Electronically Excited Cd@H2 and Cd@D2
Complexes," in The Chemical Dynamics and Kinetics of Small Radicals,
eds. B. Liu and A. Wagner (World Scientific, 1995).
105. W.H.
Breckenridge, C. Jouvet, and B. Soep, "Metal-Atom/Rare-Gas Van der Waals
Complexes," in Advances in Metal and Semiconductor Clusters, Vol. 3,
ed. M. Duncan (JAI Press, Greenwich, 1995).
106. Steven
Massick and W.H. Breckenridge, "A New Class of Strongly Bound, Doubly
Excited Valence States of Neutral Van der Waals Molecules:
Mg(3pπ,3pπ 3PJ)@Ar(3ΣG)," J. Chem. Phys.
104, 7784 (1996) [Accepted as a Communication].
107. J.-H.
Wang, H. Umemoto, Allen W. K. Leung, and W.H. Breckenridge, "Reactions of
Zn(4s4p 3P1) and Cd(5s5p 3P1)
with SiH4," J. Chem. Phys. 104, 9401 (1996).
108. Steven
Massick and W.H. Breckenridge, "A Determination of the Ionization
Threshold for the Mg(3s3p 3P0)@Ar(3Π0-) Metastable State: The Bond Energy
of MgAr+," Chem. Phys. Lett. 257, 465 (1996).
109. W.H.
Breckenridge, "Activation of Si-H, C-H, and H-H Bonds by nsnp Excited
States of Metal Atoms," J. Phys. Chem. 100, 14840 (1996).
110. Allen
W.K. Leung, Mark Roberson, Jack Simons, and W.H. Breckenridge, "Strong
Bonding in a Doubly Excited Valence State of a van der Waals Molecule,@ Chem. Phys. Lett. 259, 199 (1996).
111. Steven
Massick and W.H. Breckenridge, "Doubly-Excited Valence States of Neutral
van der Waals Molecules: Mg(3pπ,3pπ 3PJ)@Ar(3ΣG)," J. Chem. Phys.
105, 6154 (1996).
112. Steven
Massick and W.H. Breckenridge, "Spectroscopic Characterization of the
Excited Mg(3s3d 3DJ)AAr(3Π),
Mg(3s3d 3DJ)@Ar(3Δ)
and Mg(3s4p 3PJ)@Ar(3Π)
van der Waals States,@ J. Chem. Phys. 105, 9719 (1996).
113. Steven
Massick and W.H. Breckenridge, ASpectroscopic
Characterization of the 3Δ(4d), 3Π(4d), 3Σ+(4d),
and 3Π(5p) Rydberg States of the MgAr van der Waals Molecule,@ J. Chem. Phys. 106, 2171 (1997).
114. John G. Kaup and W. H.
Breckenridge, ABond Energies of MgKr+ and MgXe+
from Resonant Two-color Photoionization Thresholds,@ J. Chem. Phys. 107, 2180 (1997).
115. John G. Kaup and W. H.
Breckenridge, ABond Energies of CaAr+, CaKr+,
and CaXe+ from Resonant Two-color Photoionization Thresholds,@J. Chem. Phys.107, 4451 (1997).
116. John G. Kaup and W. H. Breckenridge, ASpectroscopic Characterization of the Metastable
4pπ 3Π0- Valence States and the 5s 3Σ+
Rydberg States of the CaAr, CaKr, and CaXe van der Waals Molecules,@ J. Chem. Phys. 107, 5283 (1997).
117. John G. Kaup and W. H.
Breckenridge, ASpectroscopic Characterization of the Singly-excited
CaAr(4dπ 3Π0), CaAr(4dδ 3Δ1)
States and the Doubly-excited CaAr(4pπ4pπ 3Σ!) State,@ J.
Chem. Phys. 107, 5676 (1997).
118. John G. Kaup and W. H.
Breckenridge, ASpectroscopic Characterization of the Excited Valence
MgKr(3dδ 3Δ1) and MgKr(3dπ 3Π0)
van der Waals States,@J. Chem. Phys.107, 6005 (1997).
119. John G. Kaup and W. H.
Breckenridge, ASpectroscopic Characterization of the Excited Valence
MgXe(3dδ 3Δ1), MgXe(3dπ 3Π0),
and MgXe(A3dσ@ 3Σ+)
van der Waals States,@ J. Chem. Phys. 107, 6014 (1997).
120. John G. Kaup, Allen W.
K. Leung, and W. H. Breckenridge, ASpectroscopic
Characterization of the Metastable 3pπ 3Π0+,0-
Valence States and the 4s 3Σ+ Rydberg States of the
MgKr and MgXe van der Waals Molecules,@ J.
Chem. Phys. 107, 10492 (1997).
121. W. H. Breckenridge, M.
D. Morse, and John G. McCaffrey, AA
Pair Potentials Study of Matrix-isolated Atomic Zinc. II. Intersystem Crossing
in Rare-Gas Clusters and Matrices, J. Chem. Phys. 109, 3137
(1998)
122. Allen W. K. Leung, John
G. McCaffrey, and W. H. Breckenridge, ASpectroscopic
Characterization of the Unusually Strongly Bound Doubly-Excited van der Waals
State, Mg(3pπ3pπ 3PJ)AKr[3Σ!], J.
Chem. Phys. 109, 7777 (1998).
123. Allen W. K. Leung, Ryan
R. Julian, and W.H. Breckenridge, AThe
Lowest Energy 3Π2,1,0+,0- and 3Σ+1,0-
Excited States of the MgANe van der Waals Molecule,@ Chem. Phys. Lett. 301, 325 (1999).
124. John G. McCaffrey, D.
Bellert, Allen W. K. Leung, and W.H. Breckenridge, ASpectroscopic Characterization of the Zn(4s2)ANe[1Σ+] and Zn(4s4pπ)ANe[1Π1] van der Waals States,@ Chem. Phys. Lett. 302, 113 (1999).
125. Allen W. K. Leung, D. Bellert,
Ryan R. Julian, and W.H. Breckenridge, AResonant
Two-Color Photoionization Threshold Measurements of the Zn+AAr Bond Strength: Model-potential Analysis of M+/Ar
Interactions,@ J. Chem. Phys. 110, 6298 (1999).
126. Allen
W. K. Leung, Ryan R. Julian, and W.H. Breckenridge, APotential Curves for the Ground States and Some
Excited States of MgNe, Mg+Ne, and Mg+2Ne van der Waals
Complexes,@ J. Chem. Phys. 110, 8443 (1999).
127. Allen
W. K. Leung, John G. Kaup, D. Bellert, John G. McCaffrey, and W.H. Breckenridge,
ASpectroscopic characterization of the Ca(4s4dδ 3DJ)ARG[3Δ1,2] van der Waals states (RG = Ar, Kr,
Xe): No >heavy-atom=
mixing of RG(ndδ) character into the wave functions,@ J. Chem. Phys. 111, 981 (1999).
128. Allen
W. K. Leung, John G. Kaup, D. Bellert, John G. McCaffrey, and W. H.
Breckenridge, ASpectroscopic Characterization of the Weakly Bound
Ca(4s4dσ 3D3)AAr[3Σ+]
State: Evidence for a Substantial Maximum in the Potential Curve at Long Range,@ J. Chem. Phys. 111, 2484 (1999).
129. Allen W. K. Leung, Ryan
R. Julian, and W.H. Breckenridge, APotential
Curves for the Ground States and Some Excited States of MgAHe, Mg+AHe and Mg2+AHe van der Waals Complexes,@ J.
Chem. Phys. 111, 4999 (1999).
130. Allen W. K. Leung, D. Bellert,
and W. H. Breckenridge, ASpectroscopic Analysis of an Unusual CaAXe[3Σ!] 7 Ca(4s4pπ 3P0)AXe[3Π0-] Transition,@ J. Chem. Phys.111, 6434 (1999).
131. Allen
W. K. Leung and W.H. Breckenridge, AAn Ab
Initio Study of the Ground States
and Some Excited States of BeRG, Be+RG and Be+2RG van der
Waals Complexes (RG = He, Ne),@J. Chem.
Phys. 111, 9197 (1999).
132. Darrin Bellert,
Katherine L. Burns, Rodric Wampler, and W. H. Breckenridge, AAn Accurate Determination of the Ionization Energy of
the MgO Molecule,@ Chem. Phys. Lett. 322, 41 (2000).
133. Mohamed Elhanine, Laure
Dukan, Philippe Maitre, W. H. Breckenridge, Steve Massick, and Benoit Soep, ASolvation of Magnesium and Singly Ionised Magnesium
Atoms in NH3 Clusters, Theory and Experiment,@ J. Chem. Phys. 112, 10912 (2000).
134. Katherine L. Burns, D.
Bellert, Allen W.-K. Leung, and W. H. Breckenridge, AThe Effects of Dispersive Cn/Rn
Attraction on M+/RG Bonding (M+ = Atomic Metal Ion, RG =
Rare Gas Atom),@ J. Chem. Phys. 114, 2996 (2001).
135. D. Bellert and W. H.
Breckenridge, AA Spectroscopic Determination of the Bond Length of
the LiOLi Molecule: Strong Ionic Bonding,@ J.
Chem. Phys. 114, 2871 (2001).
136. D. Bellert and W. H. Breckenridge, AA Resonant Two-Color Photoionization Threshold Determination
of the Ionization Energy of the LiOLi Molecule,@ Chem. Phys. Lett. 337, 103 (2001).
137. Katherine L. Burns, D.
Bellert, Allen W.-K. Leung, and W. H. Breckenridge, AM+/Rg Bonding: The Effects of M+ Permanent
Quadrupole Moments (M+ = Atomic Metal Ion; Rg = Rare Gas Atom),@ J. Chem. Phys. 114, 7877 (2001).
138. D.
Bellert, Darin K. Winn, and W. H. Breckenridge, “Dispersed Fluorescence Studies
of Linear LiOLi: A Strongly-Bound, but Very ‘Floppy’ Ionic Molecule,” Chem.
Phys. Lett. 348, 39 (2001).
139. D.
Bellert, Darin K. Winn, and W. H. Breckenridge, “Spectroscopic Determination of
the Vibrational Frequencies of the First 1B1 Excited
State of LiOLi,” Chem. Phys. Lett. 355, 151 (2002).
140. D. Bellert and W.H.
Breckenridge, ABonding in Ground and Excited States of A+ARg van der Waals Ions (A = Atom, Rg = Rare Gas Atom): A Model Potential
Analysis,@ Chemical Reviews 102, 1595 (2002).
141. D. Bellert, Darin K.
Winn, and W. H. Breckenridge, ARovibrational
Energy Levels of the LiOLi Molecule from Dispersed Fluorescence and Stimulated
Emission Pumping Studies,@ J. Chem. Phys. 117, 3139 (2002).
142. F. Spiegelman, L. Maron,
W. H. Breckenridge, J.-M. Mestdagh, and J.-P. Visticot, ATwo-electron Pseudopotential Investigation of the Electronic
Structure of the CaAr Molecule,@ J. Chem.
Phys. 117, 7534 (2002).
143. W. H. Breckenridge, P.-R. Fournier, M.-A. Gaveau, J.-M Mestdagh, and J. P. Visticot, AReactions of N2O with Lin in the Gas Phase and on the Surfaces of Large Arn Clusters,