Two-Dimensional Honeycomb Network Formed by Porphyrinatomanganese(III) and µ
4 s-Dimerized 7,7,8,8-Tetracyano-p-quinodimethane Dianion, S. Mikami, K-i. Sugiura, J. S. Miller, Y. Sakata, Chem. Lett. 413-414 (1999).Abstract
An unprecedented layered (2-D) honeycomb supramolecular structure comprised of µ
4 s-dimerized 7,7,8,8-tetracyano-p-quinodimethane dianion bridging four S = 2 substituted Mn(III)porphyrins as demonstrated with meso-tetrakis(2,4,6-trimethylphenyl)porphyrinato and has been structural characterized.
A segment of 2-D honeycomb structure of [MnIITMesP]2[TCNQ]2.4PhCl showing the
s-dimerization on [TCNE]22-.