Reviews & Overviews

1.      Organic Magnets, J. S. Miller, CRC Handbook of Chemistry and Physics, 81th ed. 12-126 - 126-129 (2000).

2.      Organic- Based Magnets, A New Frontier, A. J. Epstein, J. S. Miller, in the Proceedings of the International Francqui Symposium: Conjugated Polymers, Oligomers, and Dendrimers: From Polyacetylene to DNA, Bruxelles,Francqui Scientific Library, De Boeck Université Pub. 4,   509-528 (1999).

3.      Molecular-based Magnets, J. S. Miller, A. J. Epstein, Crystal Engineering: From Molecules and Crystals to Materials,  D. Braga, F. Grepioni, A. G. Orpen, Eds., NATO Sci. Ser. C, 528,  43-53 (1999).

4.      Molecular-based Magnets - An Epilog, J. S. Miller, Phil. Trans. R. Soc. Lond. (A) 357, 3159-

5.      Organic/Polymer Magnets, J. S. Miller, A. J. Epstein, Encyclopedia of Smart Materials. J. Harvey, Ed. John Wiley & sons, New York, 2000,  in press.

6.      Organometallic- and Organic-based Magnets:  New Chemistry and New Materials for the New Millennium, J. S. Miller, Inorg. Chem. 39, 0000-0000 (2000).

Metallomacrocycle Magnets

7.      Observation of Magnetic Ordering as high as 28 K for meso-tetrakis(4-halophenyl)porphyrinatomanganese(III) Tetracyanoethenide, [MnTXPP][TCNE] (X = F, Br, I), D. K. Rittenberg, J. S. Miller, Inorg. Chem. 38, 4838-4848 (1999).

8.      Two-Dimensional Honeycomb Network Formed by Porphyrinatomanganese(III) and µ4 s-Dimerized 7,7,8,8-Tetracyano-p-quinodimethane Dianion, S. Mikami, K-i. Sugiura, J. S. Miller, Y. Sakata, Chem.  Lett. 413-414 (1999).

9.      Structure and Magnetic Properties of Ferrimagnetic Mn(III)tetrakis(4-methoxy-tetrafluorophenyl)porphyrin tetracyanoethanide, [MnTF4OMePP][TCNE].2PhMe, D. K. Rittenberg, K-i. Sugiura,  Y. Sakata,  I. A. Guzei, A. L. Rheingold, J. S. Miller, Eur. J. Chem. 5, 1874-1881 (1999).

10.  Structure and Magnetic Properties of meso-Tetrakis(2,4,6-trimethylphenyl)porphinatomanganese(III) 2,5-Dimethyl-7,7,8,8-tetracyano-p-quinodimethanide with a 2.3 K Tc.  The First Example of cis-Coordination of a Tetracyanoquinodimethanide, K-i. Sugiura, S. Mikami, M. T. Johnson, J. S. Miller, K. Iwasaki, K. Umishita, S. Hino, and Y. Sakata, J. Mater. Chem. 10, 959-964 (2000).

11.  Products from the Reaction of meso-tetrakis(4-halophenyl)porphinatomanganese(II) and Hexacyanobutadiene, HCBD. Formation of p-[HCBD]22- Dimers, µ-[HCBD]•-, s-[HCBD]•-, and [C4(CN)5O]-, D. K. Rittenberg, K-i.Sugiura,  A. M. Arif, C. D. Incarvito, A. L. Rheingold, Y. Sakata, J. S. Miller, Chem. Eur. J. 6, 1811-1819 (2000).

12.  Large Coercivity and High Remanent Magnetization Organic-based Magnets, D. K. Rittenberg, K-i. Sugiura, Y. Sakata,  S. Mikami,  A. J. Epstein, J. S. Miller, Adv. Mater. 12, 126-130 (2000).

13.  Manganese(II) octabutoxynaphthalocyanine and its ferrimagnet electron-transfer salt with TCNE, D. K. Rittenberg, L. Baars-Hibbe, A. Böhm, J. S. Miller, J. Mater. Chem.10, 241-244 (2000).

14.  Structure and Magnetic Properties of meso-tetrakis(3,4,5-trimethoxyphenyl)-porphyrinatomanganese(III) 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodi-methenide.  The First Example of an Isolated [TCNQF4].-, M. T. Johnson, A. M. Arif, J. S. Miller, Eur. J. Inorg. Chem. 39, 0000-0000 (2000).

M[TCNE]x Magnets

15.  New High-Tc molecule-based Magnets – Magnetic Behavior of MII(TCNE)2.x(CH2Cl2) (M = Mn, Fe), M. A. Girtu, C. M. Wynn, C. R. Kmety, A. Y. Mishurov, J. Zhang, J. S. Miller, A. J. Epstein, Mol. Cryst., Liq. Cryst., 334, 539-548 (1999).

16.  Magnetic Properties and Critical  Behavior of Fe(tetracyanoethylene)2.xCH2Cl2, a High Tc Molecule-based Magnet,  M. A. Girtu, C. M. Wynn, J. Zhang, J. S. Miller, A. J. Epstein, Phys. Rev. B, 61, 492-500 (2000).

17.  Identification of [MII(arene)2]2+ (M = V, Cr) as the Key Intermediate in the Formation of V[TCNE]x.ySolvent Magnets and Cr[TCNE]x.Solvent, D. C. Gordon, L. Deakin, A. M. Arif, J. S. Miller, J. Am. Chem. Soc. 122, 290-299 (2000).

18.  Thin Film V[TCNE]x Magnets, K. I. Pokhodnya, A. J. Epstein, J. S. Miller, Adv. Mater. 12, 410-413 (2000).

19.  Synthesis and Reactivity of the Tl(I) salts of [TCNE]•- and [TCNE]2-.  The Structural Determination of Tl[TCNE] and [TDAE][TCNE]2 and Evidence for a Chelated [TCNE]•-, M. J. Johnson, C. Campana, B. M. Foxman, W. Desmarais, M. J. Vela, J. S. Miller, Eur. J. Chem. 6, 1805-1810(2000).

Metallocyanide Magnets

20.  Electron Transfer, Linkage Isomerization, Bulk Magnetic Order, and Spin Glass Behavior in the Iron Hexacyanomanganate Prussian Blue Analog, W. E. Buschmann, J. Ensling, P. Gütlich, J. S. Miller, Chem. Eur. J. 5, 3019-3028  (1999).

21.  Structure and Physical Properties of Hexacyanomanganate(III), [MnIII(CN)6]3-, W. E. Buschmann, L. Liable-Sands, A. L. Rheingold, J. S. Miller, Inorg. Chim. Acta  284, 175-179 (1999).

22.  Enhancement of the Magnetic Ordering Temperature (and Air Stability) of a Mixed Valent Vanadium Hexacyanochromate(III) Magnet to 99 oC (372 K), Ø. Hatlevik,  W. E. Buschmann, J. Zhang, J. L. Manson,  and J. S. Miller, Adv. Mater. 11, 914-918 (1999).

23.  Magnetic Order and Spin-Glass Behavior in the M[Mn(CN)6] (M = V, Cr, Mn, Co, Ni) Prussian Blue Analogs, W. E. Buschmann, J. S. Miller, Inorg. Chem. 39, 2411-2421 (2000).

Dicyanamide Magnets

24.  Collinear Ferromagnetism and Spin Orientation in the Molecule-based magnets M[N(CN)2]2 (M = Co, Ni),  C. R. Kmety, J. L. Manson, Q. Huang,  J. W. Lynn,  R. W. Erwin, J. S. Miller, A. J. Epstein, Phys. Rev. B 60, 60-63 (1999).

25.  Structures and Magnetic Properties of Novel 1-D Coordination Polymers Containing both Dicyanamide and Pyridine-type Ligands, J. L. Manson, A. M. Arif, C. D. Incarvito, L. M. Liable-Sands, A. L. Rheingold, J. S. Miller, J. Sol. State. Chem 145, 369-378 (1999).

26.  Novel 1-D Coordination Polymers Containing m-[N(CN)2]- Bridging Ligands.  Structure and Magnetic Properties of Mn[N(CN)2]2L (L = 2,2'-bipyridine, 4,4'-bipyridine), J. L. Manson, C. D. Incarvito, A. M. Arif, A. L. Rheingold, J. S. Miller, Mol. Cryst., Liq. Cryst. 334, 605-613 (1999).

27.  Observation of Spontaneous Magnetization in the M[N(CN)2]2 (M = Cr, Mn) Weak Ferromagnets, J. L. Manson, C. R. Kmety, A. J. Epstein, J. S. Miller,  Inorg. Chem. 38,  2552-2553 (1999).

28.  Crystal Structure and Magnetic Properties of Fe[N(CN)2]2(MeOH)2 - A 2-D Layered Network Consisting of Hydrogen-Bonded 1-D Chains, J.  L. Manson, A. M. Arif, J. S. Miller, J. Mater. Chem. 9, 979-983 (1999).

29.  Magnetic Phase Transitions in MII[N(CN)2]2, C. R. Kmety, J. L. Manson, Q. Huang, J. W. Lynn, R. W. Erwin, J. S. Miller, A. J. Epstein, Mol. Cryst., Liq. Cryst. 334, 631-640 (1999).

30.  Synthesis, Structure and Magnetic Properties of Co2{[N(CN)2]4bpym}·H2O an M{[N(CN)2]2bpym}·H2 (M = Mn, Fe, Co; bpym = 2,2'-bipyrimidine), S. R. Marshall, C. D. Incarvito, A. L. Rheingold  J. L. Manson, J. S. Miller, Inorg. Chem. 39, 1969-1973 (2000).

Tricyanomethane Magnets

31.  Spin Frustration in MII[C(CN)3]2 (M = V, Cr).  A Magnetism and Neutron Diffraction Study, J. L. Manson, E. Ressouche, J. S. Miller, Inorg. Chem. 39, 1135-1141 (2000).

Azide Magnets

32.  MnII(N3)2(pyrazine).  A 2-D Layered Structure Consisting of Ferromagnetically Coupled 1-D {Mn(m-1,1-N3)2}n Chains, J. L. Manson, A. M. Arif, J. S. Miller, Chem. Commun. 1479-1480 (1999).

Spin Crossover Materials

33.  Spin Crossover Behavior of [FeII(isoxazole)6][BF4]2 - A Structural Study, W. H. Hibbs, A. M. Arif, P. J. van Koningsbruggen, J. S. Miller, CrystEngComm 4 (1999)

34.  Spin Crossover Masterials, J. S. Miller, Encyclopedia of Smart Materials. J. Harvey, Ed. John Wiley & sons, New York, 2000,  in press.