Kostia Pokhodnya
Ph.D. Moscow Institute of Physics and Technology
kostia@chemistry.utah.edu
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Magnetic Thin Films
 
My specific research objectives are to design a new stable magnetic material that can be used as a working element in (a) non-volatile magnetic DRAM chips, and (b) reading and writing devices for data processing. 
 

To achieve this goal one should design a material which:

1) exhibits a substantial spontaneous magnetization at room temperature;

Figure 1.  Magnetic thin films of the V[TCNE]x magnetically order with a magnetic transition at Tc = 370 K, almost 100 oC above room temperature.

2) has an almost rectangular hysteresis loop and relatively high coercivity (~1 kOe) for chip applications; (should be done, no fundamental limitations)
 

3) has vanishing coercivity for reading/writing device applications;
 

4) can be easily processed into a thin film;

V[TCNE]x film can be deposited by CVD technique on variety of rigid and flexible substrates: glass, Si wafer, Teflon, gold, silver and aluminum foils, amorphous carbon, etc.

Figure 2. Schematic illustration of the CVD apparatus used to prepare thin films of the V[TCNE]x magnet.


5) is stable in the open air itself, or, if not very stable, can be shielded in protective layers.

V[TCNE]x film remains magnetic in air for 1h

Figure 3.  Photo of ca. 5 µm film of the V[TCNE]x magnet on a glass cover slide being attracted to a Co5Sm  magnet (ambient conditions in air).

References:

K.I. Pokhodnya, A.J. Epstein, J.S. Miller, Thin-Film V[TCNE]x Magnets, Advanced Materials, 12, Issue 6, 410, (2000).