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Contact Information

Matthew S. Sigman
315 So. 1400 E. Rm. 4253A
Salt Lake City, UT 84112
sigman@chem.utah.edu
Office: (801) 585-0774

Group News


Brian Michel's paper in JACS was highlighted in the August 2009 issue of Synfacts.

Matthew Sigman received the 2009 Robert W. Parry Teaching Award

Susi Podhajsky's paper in Organometallics was mentioned in Carmen Drahl's article "Hydrochlorination Reformation" in the July 14, 2008 edition of Chemical & Engineering News

Campus Overview

Recent Research Highlights


Gligorich, K.M.; Sigman, M.S. "Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant," Chem. Commun., 2009, 3854 - 3867

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Gligorich, K.M.; Iwai, Y.; Cummings, S.A.; Sigman, M.S. "A new approach to carbon–carbon bond formation: development of aerobic Pd-catalyzed reductive coupling reactions of organometallic reagents and styrenes," Tetrahedron, 2009, 65, 26, 5074-5083.

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Miller, J.J.; Rajaran, S.; Pfaffenroth, C.; Sigman, M.S. "Synthesis of amine functionalized oxazolines with applications in asymmetric catalysis," Tetrahedron, 2009, 65, 3110-3119.

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Michel, B. W.; Camelio, A. M; Cornell, C. N.; Sigman, M. S. "A General and Efficient Catalyst System for a Wacker-Type Oxidation Using TBHP as the Terminal Oxidant: Application to Classically Challenging Substrates," J. Am. Chem. Soc.2009, 131, 17, 6076-6077.

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Urkalan, K.B.; Sigman, M.S. "Palladium-Catalyzed Oxidative Intermolecular Difunctionalization of Terminal Alkenes using Organostannanes and Molecular Oxygen,” Angew. Chem., Int. Ed. 2009, 48, 3146-3149.

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